Point groups
Point groups are a way of classifying molecules in terms of their internal symmetry.
Molecules can have many symmetry operations that result into indistinguishableconfigurations.
Different collections of symmetry operations are organized into groups.
These 11 groups were developed by Schoenflies.
C1:only identity. Example: CHBrClF
Cs:only a reflection plane. Example: CH2BrCl
Ci:only a center of symmetry. Example: staggered 1,2-dibromo-1,2-dichloroethane.
Cn:only a Cn center of symmetry.
Example of C2: hydrogen peroxide (not coplanar)
Cnv:only n-fold axis and n vertical (or dihedral) mirror planes.Example of C2v: water; of C3v: ammonia
Cnh:only n-fold axis, a horizontal mirror plane, a center of symmetry or animproper axis.Example of C2h: trans dichloroethylene; of C3h: B(OH)3.